Alliance is a city in eastern Stark County, Ohio, United States, with a small district lying in adjacent Mahoning County. The population was 21,67…Alliance is a city in eastern Stark County, Ohio, United States, with a small district lying in adjacent Mahoning County. The population was 21,672 as of the 2020 census. The city is approximately 16 miles northeast of Canton, 27 miles southwest of Youngstown and 51 miles southeast of Cleveland.
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