Transition metals have many applications in engineering, electrochemistry and catalysis. To understand their properties, the interplay between atomic localization and delocalization of the outer ...
Valence tautomerism (VT) in transition metal complexes is a fascinating phenomenon in which reversible intramolecular electron transfer between the metal centre and a redox‐active ligand results in ...
Metal valence state was identified as a key factor steering the anion reactivity and thus “indirectly” affecting the Li-bond strength, which further determined the conversion kinetics of lithium (poly ...